Every year some players opt to go the college route instead of signing. I've listed 29 names that could make that decision and be eligible in 2015 or 2014 where listed. The % chance is based on what I have heard or how other players have decided. I have no personal insight on this with any player, just my hypothesis and a short reason why I feel that way.
| % Chance to College | Name | POS | Commit | Reason |
| 100 | Nathan Kirby | P | Virginia | Already opted out of draft |
| 95 | Jameis Winston | OF | Florida State | Quarterback at FSU |
| 95 | Anthony Alford | OF | Southern Miss | Two sports at So. Miss is the plan |
| 90 | Freddy Avis | P | Stanford | Very smart individual values education highly. |
| 80 | CJ Hinojosa | SS | Texas | Shoulder injury and strong commit |
| 70 | Dansby Swanson | SS | Vanderbilt | Very good student and tough school to sign players from |
| 70 | Nick Williams | OF | Texas | May even go JuCo with stock sliding |
| 70 | Drew Jackson | SS | Stanford | Very good student and tough school to sign players from |
| 60 | Alex Bregman | C | LSU | Strong commitment and injury |
| 60 | Taylore Cherry | P | North Carolina | Sliding stock |
| 50 | Lucas Giolito | P | UCLA | Elbow injury and high bonus demands |
| 50 | Tucker Simpson | P | Florida | Could be in 2014 draft as sophomore |
| 40 | Trey Williams | 3B | Pepperdine | Sliding stock and great school |
| 40 | Duane Underwood | P | Georgia | Sliding stock and very raw |
| 40 | Xavier Turner | 3B | Vanderbilt | May be under drafted and going to a great school |
| 30 | Lance McCullers | P | Florida | Doesn't need to sign. Could be top 5 in 2015. |
| 30 | Walker Weickel | P | Miami | Sliding stock. Could be high pick in 2015. |
| 30 | Stryker Trahan | C | Ole Miss | All depends on where he is drafted. |
| 30 | Rio Ruiz | 3B | USC | Injury may cause slide |
| 30 | Clate Schmidt | P | Clemson | Sliding stock |
| 30 | Fernelys Sanchez | OF | Central Arizona CC | Injury may cause slide |
| 30 | Ty Moore | OF/P | UCLA | UCLA is a strong school, could be a two way player |
| 30 | Walker Buehler | P | Vanderbilt | Vandy is hard to sign people away from. |
| 30 | James Marvel | P | Duke | Could improve a lot in college. |
| 30 | Chase Mullins | P | Kentucky | Could improve a lot in college. |
| 30 | Hunter Virant | P | UCLA | UCLA should get at least one very good arm. |
| 30 | Daniel Robertson | 3B | UCLA | Depending on where he's drafted. |
| 30 | Tyler Gonzales | P | Texas | Could be in 2014 draft, could be 1st rounder then |
| 30 | Rock Rucker | P/1B | Auburn | Could be in 2014 draft, could be two way guy |
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